Hydrated goethite (α-FeOOH) (1 0 0) interface structure: Ordered water and surface functional groups     

Sanjit K. Ghose  Glenn A. Waychunas  Peter J. Eng 《Geochimica et cosmochimica acta》2010,74(7):1943-2587

Goethite(α-FeOOH), an abundant and highly reactive iron oxyhydroxide mineral, has been the subject of numerous studies of environmental interface reactivity. However, such studies have been hampered by the lack of experimental constraints on aqueous interface structure, and especially of the surface water molecular arrangements. Structural information of this type is crucial because reactivity is dictated by the nature of the surface functional groups and the structure or distribution of water and electrolyte at the solid-solution interface. In this study we have investigated the goethite (1 0 0) surface using surface diffraction techniques, and have determined the relaxed surface structure, the surface functional groups, and the three dimensional nature of two distinct sorbed water layers. The crystal truncation rod (CTR) results show that the interface structure consists of a double hydroxyl, double water terminated interface with significant atom relaxations. Further, the double hydroxyl terminated surface dominates with an 89% contribution having a chiral subdomain structure on the (1 0 0) cleavage faces. The proposed interface stoichiometry is ((H₂O)(H₂O)OH₂OHFeOOFeR) with two types of terminal hydroxyls; a bidentate (B-type) hydroxo group and a monodentate (A-type) aquo group. Using the bond-valence approach the protonation states of the terminal hydroxyls are predicted to be OH type (bidentate hydroxyl with oxygen coupled to two Fe³⁺ ions) and OH₂ type (monodentate hydroxyl with oxygen tied to only one Fe³⁺). A double layer three dimensional ordered water structure at the interface was determined from refinement of fits to the experimental data. Application of bond-valence constraints to the terminal hydroxyls with appropriate rotation of the water dipole moments allowed a plausible dipole orientation model as predicted. The structural results are discussed in terms of protonation and H-bonding at the interface, and the results provide an ideal basis for testing theoretical predictions of characteristic surface properties such as pK_a , sorption equilibria, and surface water permittivity.  相似文献   

Field geology on the Moon: Some lessons learned from the exploration of the Haughton impact structure, Devon Island, Canadian High Arctic     

Gordon R. Osinski  Pascal Lee  Kelly Snook  Darlene S.S. Lim 《Planetary and Space Science》2010,58(4):646-48

With the prospect of humans returning to Moon by the end of the next decade, considerable attention is being paid to technologies required to transport astronauts to the lunar surface and then to be able to carry out surface science. Recent and ongoing initiatives have focused on scientific questions to be asked. In contrast, few studies have addressed how these scientific priorities will be achieved. In this contribution, we provide some of the lessons learned from the exploration of the Haughton impact structure, an ideal lunar analogue site in the Canadian Arctic. Essentially, by studying how geologists carry out field science, we can provide guidelines for lunar surface operations. Our goal in this contribution is to inform the engineers and managers involved in mission planning, rather than the field geology community. Our results show that the exploration of the Haughton impact structure can be broken down into 3 distinct phases: (1) reconnaissance; (2) systematic regional-scale mapping and sampling; and (3) detailed local-scale mapping and sampling. This break down is similar to the classic scientific method practiced by field geologists of regional exploratory mapping followed by directed mapping at a local scale, except that we distinguish between two different phases of exploratory mapping. Our data show that the number of stops versus the number of samples collected versus the amount of data collected varied depending on the mission phase, as does the total distance covered per EVA. Thus, operational scenarios could take these differences into account, depending on the goals and duration of the mission. Important lessons learned include the need for flexibility in mission planning in order to account for serendipitous discoveries, the highlighting of key “science supersites” that may require return visits, the need for a rugged but simple human-operated rover, laboratory space in the habitat, and adequate room for returned samples, both in the habitat and in the return vehicle. The proposed set of recommendations ideally should be tried and tested in future analogue missions at terrestrial impact sites prior to planetary missions.  相似文献   

Studies on groundwater recharge characteristics at a reclaimed land site with an equatorial climate using time‐series and spectral analyses     

Stephen Boon Kean Tan  Eng Ban Shuy  Lloyd Hock Chye Chua  Woon Kang Yee 《水文研究》2007,21(7):939-948

Groundwater recharge studies are essential for investigating the feasibility of using the reclaimed lands in Singapore for subsurface storage and recovery of water. Through time‐series and spectral analyses, net recharge percentages and stress‐filtering characteristics at the reclaimed land were found to depend strongly on the stress transfer velocity, which was a combined function of rainfall pattern and vadose zone thickness. Based on stress transfer velocity, a theory was established to provide logical explanations for the rainfall–recharge relationship, the observed stress‐filtering characteristics and the recharge percentage characteristics at the unconfined sandy aquifer. Although the reclaimed land site has a lithollogically homogeneous soil profile, a non‐uniform recharge pattern was observed to be influenced pronouncedly by the uneven density distribution of bush grasses. Under a bare soil condition, significantly lower recharge percentages were observed for areas under the influence of offshore tides. The unconfined sandy aquifer appears to dampen out the wave propagation of offshore tides rapidly within a short distance from the tidal source, though it has a fairly straight shoreline and is created from highly compacted sand fills. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

Tidal modification and its effect on sluice-gate outflow after completion of the Saemangeum dike,South Korea     

Seok Lee  Heung-Jae Lie  Kyu-Min Song  Cheol-Ho Cho  Eun-Pyo Lim 《Journal of Oceanography》2008,64(5):763-776

This study examined tidal modification and change in tidal currents caused by the construction of the Saemangeum dike, based on field observations and a numerical model. The Saemangeum dike was completed in April 2006, enclosing an estuarine area along the mid-western coast of South Korea. After closure of the dike, the tidal range outside the dike decreased slightly but significantly, while the inside tidal range decreased drastically. The numerical model results show that the dike construction has influenced tidal energy propagation and the tidal system in the Yellow Sea. The tidal current speed near the dike decreased abruptly following closure of the dike, except in front of the sluice gates. Since completion of the dike, outflow water discharged from the sluice gates has longer residence times due to the weakened tidal current; the change in the tidal current field has also caused greater northward expansion of outflow water. The sluice gates release fresher water, which spreads over the sea surface mainly by inertial momentum near the gate; this water is then gradually mixed with sea water farther from the gate. The less saline, possibly more contaminated outflow impacts the marine environment near the Saemangeum dike. Controlling the discharge and gate-opening timing can partially mitigate these impacts on the marine environment.  相似文献   

Earthquake doublets in the Solomon Islands     

Thorne Lay  Hiroo Kanamori 《Physics of the Earth and Planetary Interiors》1980,21(4):283-304

Large, shallow, thrust earthquakes in the Solomon Islands region tend to occur in closely related pairs. Two recent sequences are July 14, 1971 (M_S = 7.9) and July 26, 1971 M(_S = 7.9) and 14^h37^m, July 20, 1975 (M_S = 7.9) and 19^h54^m, July 20, 1975 (M_S = 7.7). The mechanism of these seismic doublets has important bearing on the triggering mechanism of earthquakes in subduction zones. Detailed analysis of the seismic body waves and surface waves were performed on the 1971, 1974, and 1975 doublets, providing a better understanding of: (1) the mechanics of seismic triggering, (2) the state of stress on the fault plane, and (3) the nature of subduction between the Pacific and Indian plates. The results indicate that although the geometry of the subduction zone in the Solomon Islands is complicated by the presence of several sub-plates, the slip direction of the Indian plate with respect to the Pacific plate is relatively uniform over the entire region. The large seismic moments of the 1971 sequence (1.2 · 10²⁸ and 1.8 · 10²⁸ dyne cm) indicate that these events directly represent the underthrusting of the Indian and Solomon plates beneath the Pacific plate. The body waves from these doublets, recorded on the WWSSN long-period seismograms, are remarkably impulsive and simple compared with those from events of comparable seismic moment in other subduction zones. In addition, the source dimensions of the body waves are 30–70 km in length, substantially smaller than the overall rupture surfaces radiating the surface waves which are 100–300 km in length. These facts suggest the existence of relatively large, isolated high-stress zones on the fault plane. This type of stress distribution is distinct from other regions which have more heterogeneous stress distribution on the fault plane, and this is proposed as the principal characteristic of this region responsible for the occurrence of the doublets and for the apparent efficiency of triggering in the Solomon trench. Prior to the 1971 sequence, similar sequences have occurred in the same area in 1919–1920 and 1945–1946. From the amount of slip (1.3 m) determined for the 1971 sequence and the apparent recurrence interval of 25 years, a seismic slip rate of 5 cm yr^?1 is determined. This value is a significant portion of the convergence rate between the Indian and Pacific plates indicating that the plate motion here is taken up largely by seismic slip.  相似文献   

Pilot-scale field model tests for detecting landfill leachate intrusion into the subsurface using a grid-net electrical conductivity measurement system     

Myoung?Hak?Oh  Ju?Hyung?Lee  Gil?Lim?Yoon  Junboum?ParkEmail author 《Environmental Geology》2003,45(2):181-189

The grid-net electrical conductivity measurement system for detecting exact locations of landfill leachate intrusion in the subsurface was developed in this study. Laboratory and pilot-scale field model tests were performed to evaluate the direct application of a grid-net electrical conductivity measurement system for the detection of landfill leachate. A significant increase in electrical conductivity of soil was observed by adding landfill leachate. This can be explained as an increase in electrical conductivity of pore fluid due to an increase in leachate constituents as charge carriers. In pilot-scale field model tests, leachate intrusion locations were accurately identified at the initial stage of landfill leachate release by the grid-net electrical conductivity measurement system. The electrical conductivity of the subsurface before leachate injection lay within a small range of 24.8–43.0 S/cm. The electrical conductivity values in detected points were approximately ten times more than the conductivity values of the subsurface without landfill leachate intrusion. The results in this study indicate that the grid-net electrical conductivity measurement method has a possible application for detecting locations of landfill leachate intrusion into the subsurface at the initial stage, and thus has great potential in monitoring leachate leakage at waste landfills.  相似文献   

Reply by authors to E. kausel     

Y. K. Chow  S. Swaddiwudhipong  S. A. Lim 《地震工程与结构动力学》1989,18(7):1085-1085

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Adaptive bang–bang control for the vibration control of structures under earthquakes     

C. W. Lim  T. Y. Chung  S. J. Moon 《地震工程与结构动力学》2003,32(13):1977-1994

An adaptive method based on the modified bang–bang control algorithm is proposed for the vibration control of structures subjected to unexpected severe seismic loads greater than the design loads. A hydraulic‐type active mass damper was made and experiments were carried out in the laboratory using a one‐story test structure and a five‐story test structure with the active mass damper. Through numerical simulations and experiments it was confirmed that the proposed method works well to suppress the vibration of structures subjected to unexpected severe seismic loads greater than the design loads without causing any unstable situations. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

Uptake and transfer of14C-simetryne through the laboratory freshwater food chain     

Xu Ying  J. P. Lay  Zhang Yongyuan 《中国海洋湖沼学报》1989,7(1):10-16

This paper deals with the bioconcentration of¹⁴C-simetryne from water by aquatic test organisms: green algae—Monoraphidium minutum, rotifers—Brachionus rubens, daphnids—Daphnia magna, and fish—Brachydanio rerio. The chemical was bioconcentrated rapidly in all test species during the first 48 hours of experiment. The BCF values (bioconcentration factor) from all uptake studies show that simetryne has higher accumulation in algae than in rotifers, daphnids and zebra fish. The logarithm of the n-octanol/water partition coefficient of simetryne measured as 2.06±0.05 was correlated with the BCFs in the organisms as based on the lipid contents. ¹⁴C-simetryne uptake via the food-chain amounted to only 22% to 42% of the bioconcentration from water. Clearance of¹⁴C-derived residues from fish was rapid with a half-life of 2.1 days. This project is a part of a cooperation program between the Institute of Hydrobiology, Academia Sinica, Wuhan, and the Institut fur Okologische Chemie, GSF, F. R. Germany, and is supported by the Natural Science Foundation of Academia Sinica.  相似文献   

Fabric and crystal characteristics of Bohai and Arctic sea ice   总被引：1，自引：0，他引：1  

李志军  康建成  蒲毅彬 《极地研究(英文版)》2002,13(1)

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